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2581

SCIENCE

[Entered at the Post-Office of New York, N. Y., as Second-Class Matter.]

A WEEKLY NEWSPAPER OF ALL THE ARTS AND SCIENCES.

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ELECTRIC ACCUMULATORS.

THE world moves slowly, - faster, perhaps, than formerly, - but still the movement is well ordered and regular, new things not jumping into existence fully developed and ready for their most advantageous use.

All this is true of the accumulators or storage-batteries for electricity, about which the public has heard for a number of years. The principle on which they are based is an old one. That an electric current, in passing through many chemical solutions, would decompose them, is a fact shown in every school in the land. That

SINGLE COPIES, TEN CENTS. $3.50 PER YEAR, IN ADVANCE.

store up its electricity? The answer to these questions is well
given in a paper by George B. Prescott, jun., read at a meeting
of the American Institute of Electrical Engineers on Oct. 29.
There are in use electrical systems for lighting purposes; and, as
every one knows, these are mainly of service after the sun goes
down, and then they are called on for a maximum service for a
short time, which is followed by a smaller demand during the rest
of the night. It is patent that such a method of production can-
not be economical, for the plant must be idle, or working to but a
fraction of its capacity, most of the time. The accumulator comes
in as a storehouse; so that the dynamos may be run at an even

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FIG. 1. ELECTRICAL ACCUMULATOR COMPANY'S STORAGE-BATTERY.

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when the battery sending the current is removed, and the wires entering the solution joined, a current can be detected in these wires opposite in direction to the original current, is also known. The decomposing apparatus shows itself as a storage-battery from which, to all intents and purposes, electricity runs out again when the experiment of electrolysis is over. What those interested in storage-batteries have been doing is to make this effect of commercial value.

But why should this effect be of commercial value at all? Why not use the current from the primary battery itself, and not first

rate of production, and any spare electricity stored till the extra demand has to be met.

There is a field, then, in which accumulators may play an important part, not in competition with the direct application of the current from the dynamo, but standing to the electric-light systems very much as gasometers do to gas-works. The demand for light during the day is not nil, yet it is so small that few electric-light companies are justified in running their dynamos the twenty-four hours through. But it is calculated that there will be ample surplus of current to charge the necessary storage-batteries if the

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to the average, it is found in practice that some series will become fully charged sooner than others.

The details of the methods of use we hope to publish later. Our illustrations show the battery and street-car of the Electric Accumulator Company; this car, as is well known, calling for no street wires.

MAGNOLIA-METAL.

FOR the last fifty years the soft metal made of copper, regulus of antimony, and tin, invented by Isaac Babbitt of Boston, and named for him, has been in use for the bearings in machinery, as the friction was much reduced by its use.

posed to be the best of their class. The machine used was a 5inch shaft keyed on a 3-inch shaft lubricated with sperm-oil, 5-inch shaft running in the oil. With light pressure and slow revolutions of shaft, the metals showed little difference, but, with rapid revolutions and heavy pressures, magnolia-metal showed great superiority. The foregoing table shows a detailed statement of the tests, which occupied an hour's time.

The testing-machine consists of a shaft revolving in suitable bearings, between two of which is a steel journal on which the test-piece is placed; the top half only of the bearing being used, which was lined with the metals tested. The brass sets in a frame, to the under side of which is suspended a platform. On

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this platform the weights are placed for producing the pressure. There are two knife-edges, allowing freedom of the frame, and the weighted platform. A pan beneath the test journal, carrying oil, lubricated the bearing. Thermometers were inserted in the oilbath and in a recess in the top of the metal. In this machine the co-efficient of friction is obtained by the angle of deviation of the knife-edge from a vertical line passing through the centre of the journal in terms of the radius of the journal, and is independent of the weight entering directly into this calculation.

Other satisfactory tests have been made by the United States Government at the Brooklyn Navy Yard, and by Professor R. H.

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1,000 1,500 1,965"

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1,500 1,965 " 1,000 1,500 1,965 1,000 1,500 1,965" 1,000 1,500 1,965"

Magnolia ran full time free without melting out or stopping machinery; Hoyt's melted and stuck to shaft at end of 45 minutes; de-oxidized genuine Babbitt melted and stuck to shaft at end of 55 minutes.

Mr. H. G. Torrey, who has been assayer at the United States Mint, New York, for thirty years, has made several friction tests of journal-bearing metals, the results of which have just been made known. Those selected were magnolia-metal, and Hoyt's genuine Babbitt and the de-oxidized genuine Babbitt, the latter two sup

FIG. 2.

MAGNOLIA-METAL BEARING.

Smith of Mason College, Birmingham, England, who reports that his tests show the metal to be superior to either Babbitt or gunmetal, producing less friction, keeping the bearing temperature lower, requiring less lubrication, and possessing greater durability.. Professor Smith says that the longer the magnolia-metal bearing is used, and the more severe the duty imposed on it, the better becomes its condition.

Recently this new metal has been introduced in the "City of Paris" and the "Augusta Victoria," contributing its share in the speed developed by these ocean racers.

ATMOSPHERIC NITROGEN AS PLANT-FOOD.

FARMERS in all older portions of the country buy large quantities of nitrogen in artificial fertilizers. Nitrate of soda, sulphate of ammonia, dried blood, cottonseed-meal, and fish-scraps owe their fertilizing value mainly, and Peruvian guano and tankage largely, to nitrogen; and the same element is one of the chief ingredients of bone manures, ammoniated phosphates, and many other fertilizers. According to an estimate by the Connecticut Experiment Station, not less than five hundred thousand dollars are expended annually for commercial fertilizers in Connecticut. A large amount of this goes for nitrogen, which is one of the dearest of the ingredients of fertilizers, and costs at retail from eight or ten to eighteen cents or more a pound.

The Storrs School Agricultural Experiment Station, Mansfield, Conn., în its October bulletin, reports a continuation of an investigation of atmospheric nitrogen as plant-food, begun some years ago at Wesleyan University, Middletown, where the chemical work of the station has been carried on since the establishment of the latter in 1888. The details of the experiments there reported were conducted by Mr. C. D. Woods, formerly assistant in chemistry in Wesleyan University, and now chemist of the station.

The quantities of nitrogen in ordinary crops, and the cost of the same in the better commercial fertilizers, vary from 31.5 pounds for potatoes, to 80.3 pounds for clover-hay, costing from $4.73 to $12.05.

The plants must have this nitrogen, or they cannot grow. They obtain part of it from the soil, and the rest from the air. The nitrogen of the soil has either been accumulated in the past or is supplied in manures. A small quantity, in the form of ammonia and other compounds of nitrogen, is continually brought to the soil by rain or snow. Late research implies that soils acquire nitrogen from the air by the aid of microbes or electricity, or probably both. The nitrogen in the soil is being continually leached away by drainage-waters, and more or less of it escapes into the air. Soils which are not cultivated, and from which the produce is not removed, accumulate more nitrogen than they lose, so that many virgin soils have a large stock. By ordinary cultivation and cropping, the nitrogen is gradually exhausted, unless it is returned by manures or otherwise.

The main questions have been, first, Can plants make use of atmospheric nitrogen to any considerable extent? second, If they do, is it the free nitrogen of the air that they acquire ? There are certain kinds of plants, like clover, beans, and others belonging to the family of the legumes or Papilionacea, which generally get on very well without nitrogenous fertilizers in worn-out soils; and it would seem as though these plants, at any rate, must in some way be able to make use of the nitrogen of the air. But the classic experiments of Boussingault in France, of Lawes and Gilbert in England, and others, have been widely accepted as proving that plants cannot use the free nitrogen of the air, and that they get practically very little combined nitrogen from the air, so that they are dependent upon that previously stored in the soil or supplied in manures. Still many experimenters have not regarded the question as definitely settled.

While the experiments of Boussingault, and Lawes and Gilbert, differ in their details, they agree in this, that the plants were under conditions widely different from those in ordinary culture. The especial object was to find whether plants acquire free nitrogen; and the plants were for the most part grown under cover, to exclude combined nitrogen, and in artificial soil containing little or no nitrogen. The growth was generally stunted and abnormal.

Later experiments on more or less similar plans have brought similar results. Investigations by Ville in France, however, implied that plants can acquire nitrogen from the air, but his conclusions were not generally accepted.

Some years ago a series of experiments was conducted by Mr. C. D. Woods, in which the conditions were more like those in which plants commonly grow. The method used was that of sand-culture. By proper management, feeding, and watering, plants may be grown as large, as healthy, and in every way as well developed, in pure sand as in the richest soil. For these experiments sea-sand was used. To remove all traces of material containing nitrogen

(except, of course, air), the sand was carefully sifted, then washed, and finally heated in iron pots in a furnace, so hot that the pots nearly melted. It was then put in glass jars, and water was added in which were dissolved salts containing the mineral elements of plant-food, potash, lime, iron, sulphuric acid, phosphoric acid, etc., and in some cases nitrogen in the form of nitrate of potash or lime. The seeds were then sown, and the plants grew. They were kept in the open air in a building erected for the purpose. The arrangement was such that the plants were exposed in the day-time in pleasant weather, but put under cover when it rained and at night. They had enough plant-food to enable them to make more or less growth independently of the nitrogen of the air, but were free to get the nitrogen from the air in case they were able to do so. They grew well. Many of them were as well or better developed than those in a rich garden-soil near by.

The amount of nitrogen in the seeds and in the nutritive solutions was determined by analyses at the beginning of the experiments. The same was done with the nitrogen in the plants at the end of the experiments, and with that left in the nutritive solutions. The quantities of nitrogen supplied to the plants at the beginning, and contained in them at the end, of the experiment were thus determined. The plants were found to contain more nitrogen than had been supplied by the nutritive solutions and the seeds. For this gain there was but one possible source, the atmosphere. The peas had in some way acquired nitrogen from the air, and in some cases the quantities of atmospheric nitrogen, thus obtained were very large.

Since that time a number of investigators have obtained similar and even more striking results, and much light has been thrown upon the ways by which the plants are enabled to obtain the nitrogen from the air.

Professor Hellriegel in Germany has found from a large number of experiments that pea, lupine, and serradella plants obtain large quantities of nitrogen from the air, while oats, barley, and buckwheat seem to be restricted to that supplied to them in the soil and obtained through the roots. He has furthermore brought out the very important fact that there is a connection between the nitrogen acquired and the tubercles which are found on the roots of leguminous plants. The root-tubercles are the bulb-like enlargements, from the size of a pin-head to that of a pea or larger, sometimes called "warts," which are found on the roots of beans, peas, clover, cow-peas, and other leguminous plants. They are often thought by persons not botanists to be indications of disease. This suggests that minute organisms, termed "microbes," which are in some way connected with these tubercles, may be the agents by which the plants obtain nitrogen from the air.

To test the influence of the microbes in the soil, Professor Hellriegel prepared soil-infusions by putting small quantities of soil in water, shaking the mixture thoroughly, and letting it settle. The water was then assumed to contain the microbes. The infusions thus prepared were put into the sand in which the plants grew. In a very remarkable series of trials it was found that where leguminous plants were supplied with mineral but no nitrogenous food, and received these infusions, they grew well, had tubercles upon their roots, and contained large quantities of nitrogen when mature. Those which received no infusions, or infusions which had been sterilized, i.e., in which the microbes had been killed, made very little growth, had few or no tubercles, and showed no gain of nitrogen. In another experiment Professor Hellriegel grew peas and buckwheat inside a large glass globe, as Boussingault had done, except that soil-infusions were added. In both Hellriegel's and Boussingault's experiments the plants had practically no nitrogen except that in the seed and the free nitrogen of the air. Boussingault's plants made very little growth, and showed no gain of nitrogen. The same was true of Hellriegel's buckwheat; but his peas grew well, and gained considerable nitrogen. In other words, where the microbes were present, the peas evidently utilized the free nitrogen of the air.

Professor Wolff in Germany has reported experiments with clover which imply acquisition of atmospheric nitrogen. Numerous other late experiments indicate that both plants and soil obtain nitrogen from the air.

The experiments now described in this bulletin may be divided

into the following series: 1888, Champion of England peas, 25 trials; 1888-89, alfalfa, 5; 1889, East Hartford Early peas, first series, 33; 1889, Champion of England peas, 16; 1889, oats, 10. Other series with other plants are begun, but are not yet ready to be reported upon. The following questions were proposed for study: 1. May plants grown under normal conditions acquire any considerable amount of nitrogen, free or combined, from the surrounding atmosphere? 2. What effect has the addition of soilinfusions upon the formation of root-tubercles? 3. Is there a definite relation between the formation of root-tubercles and the acquisition of atmospheric nitrogen?

The method was essentially the same as in the previous experiments by Mr. Wood above described. The plants were grown in glass jars containing sand, purified by washing and igniting. Nutritive solutions, either free from or containing known quantities of combined nitrogen in the form of nitrate of potash or lime, were applied to the sand. The amounts of nitrogen supplied in nutritive solutions and seed were compared with the amounts found at the end of the experiments in residual solutions and plants. The difference between these two amounts must show the loss or gain in nitrogen. A loss must indicate decomposition of either the organic nitrogen of the seed or plants or the nitric acid of the nitrates fed, or both. A gain must represent the nitrogen acquired from the air in excess of any lost either from organic matter of seed or plant or from nitrate of the food.

The conditions of growth were varied by varying the amounts of nitrogen supplied in nutritive solutions. The minerals needed for the growth of the plants were added in amounts to make one part or less by weight of dissolved salts in one thousand parts of the solution. Some of the plants received no combined nitrogen except that in the seed; to others nitrates were added, but in such small quantities that the minerals were relatively in excess; to others enough nitrogen was added to make the mixture of plant-food correspond more nearly to the composition of the plants. The answer to the question, "May plants grown under normal conditions acquire any considerable amount of nitrogen from the atmosphere?" coincides with the earlier experiments at Mansfield, and is plain and unmistakable. Peas of small, early variety (Early Hartford) planted in sand, with no nitrogenous food except that in the seed, grew to a height of over five feet. With nitrogen supplied in the solutions, they sometimes reached a height of over eight feet. Many of the peas and alfalfa plants accumulated large quantities of nitrogen from the air. In one case a single plant thus obtained more than one-third of a gram (54.6 grains) of nitrogen.

In a number of experiments with peas in which the roots had few or no tubercles, instead of gain, there was a decided loss of nitrogen. This gives added force to the suggestion that if nitrogen escaped in some of the trials, it may have escaped to some extent in other cases also. If so, the results are all inaccurate as indications of the actual atmospheric nitrogen acquired, and the plants must have really obtained more than the figures imply.

It may be that the loss of nitrogen is greater in some classes of plants than in others. The apparent loss in the experiments with peas was about as large when they were not fed combined nitrogen, other than that in the seed, as when they were fed considerable quantities of nitrates. In the experiment with oats the results were very different. Without the addition of nitrates, there was no loss, but a slight gain. When nitrates were fed, there was loss; and the larger the amount of nitrates added, the greater was the loss of nitrogen.

These experiments do not tell to what extent the loss observed with the oats, and with the peas which had no root-tubercles, was from the seed, and to what extent from the nitrates; whether, as seems most likely, it was due to the action of microbes; or what connection there may be between plants of different species and the loss of nitrogen. These and kindred questions must remain for future research to decide. But one can hardly help coupling this observation of the large loss of nitrogen in the oat experiments with the common observation of practical farmers that oats are an exhaustive crop. The power of leguminous plants to acquire nitrogen from the air evidently explains in part why they are such valuable " renovating crops."

Experiments by Berthelot and others imply that nitrogen is being continually gathered from the air by soils, and that microbes, and probably electricity, aid the process. A large amount of late research tends to show that nitrogen compounds in the soil are being constantly decomposed by the action of microbes, and that the nitrogen thus set free escapes into the air.

In Hellriegel's experiments the development of the root-tubercles on the plants seemed to be dependent upon the addition of soil-infusions in those of the Storrs School Station, although the sand and water were sterilized, root-tubercles were often abundant where no soil-infusions were added. This was especially the case where the plants had some nitrogenous food. Indeed, where the plants were reasonably well fed, so far as the root-tubercles were concerned, it made no apparent difference whether they had soil-infusions or not; nor was there much difference where the plants had no nitrogen in their food. The plants were grown near a garden in which the soil was rich; and the microbes, which seem to be connected with the root-tubercles, were probably abundant. The most natural explanation is, that the organisms or their germs (spores) were floating in the air; found their way to the pots in which the plants were cultivated, and grew there; and that the growth of the microbes was especially favored where the plants had nitrates, i.e., had food enough to keep them vigorous until the tubercles were formed.

These experiments, like those of Hellriegel, reveal a remarkable relation between root-tubercles and the acquisition of nitrogen from the air by plants. Leguminous plants thus far experimented with have root-tubercles, and acquire atmospheric nitrogen. Other plants have been found to be without root-tubercles, and to gain little or no nitrogen; while in some experiments, as in those with oats, above cited, there is a large loss. There is an evident connection between root-tubercles and microbes, though the exact nature of the microbes and their connection with the tubercles remain to be explained.

While there is as yet no positive proof that the root-tubercles or the microbes are the cause of the gain of nitrogen, the fact that there is a connection between the root-tubercles and the amount of nitrogen acquired by the plants from the air is unmistakable. In every case, without exception, where there were no root-tubercles, there was loss of nitrogen; where there were "few" tubercles, there was sometimes a slight loss of nitrogen, at other times a slight gain; with a “fair number" of tubercles, there was a decided gain; where there was a "large number" of tubercles, the gain of nitrogen was very large.

It may be that this relation holds in fields as well as in pot-culture. The past season the station grew a half-acre of cow-peas, which yielded at the rate of about eight tons of green fodder per acre. In some ten different places in the field the roots were examined, and found to be covered with tubercles of large size. At one end of the field, where the yield was relatively light, the roots had less tubercles than elsewhere, and in general where the growth was heaviest the tubercles seemed to be most abundant.

As to whether the nitrogen which the plants obtain is the free or the combined nitrogen of the air, these experiments do not bring absolute proof, but the quantities of nitrogen obtained are so very large as to leave little doubt that it is free nitrogen; and the experiments of Hellriegel above cited would seem to prove that the uncombined nitrogen can thus be used. This and the cognate question as to how the nitrogen is acquired, demand further study. Investigations in this line are being planned for at the station.

This subject has a wider significance than what has been said above implies. The future welfare of our race, material, intellectual, and moral, depends upon the food-supply, or, in other words, upon the product of the soil. This, in turn, reduces itself essentially to a question of phosphoric acid, potash, and nitrogen. Enough of the first two for indefinite time to come is assured in the deposits of phosphates and potash salts already discovered, but the probability of a sufficient supply of nitrogen has been questioned. This costliest of the fertilizing elements escapes from our soils into the air and into the sea, and is taken away by crops, and not completely returned. Artificial fertilizers promise to meet but

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